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There are many other occupations in education working with children that aren't teaching jobs. Some suggestions:
-school social worker
-special education liaison
-dean of students
Yes, there are plenty of opportunities such as education specialist, behavior analyst to name few. I am not an expert in this area but did some research for you. I was able to find some interesting career prospects in Fed Govt, healthcare etc. Please see if the following links give you some idea or pointers.
behavior analyst - search in www.indeed.com
Hope this helps. Please let me know if you have any questions.